| 241818-93-9

• CAS: 241818-93-9
• 化学式: C₃₂H₂₄Cl₄N₄Pd₂
• 分子量: 819.221
• InChiKey: CMWQEVFQKMCOAD-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(3-吡啶-2-基苯基)吡啶 、 lithium chloride 、 palladium dichloride 以 甲醇 、 溶剂黄146 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Divergent Behavior of Palladium(II) and Platinum(II) in the Metalation of 1,3-Di(2-pyridyl)benzene

  摘要：

  1,3-Di(2-pyridyl)benzene undergoes regioselective orthometalation with Pd(OAc)(2) on the central ai yl ring, giving rise to a dimeric complex in which four acetate units act as bridges between two doubly metalated ligands and each pyridine ligand coordinates to a different metal atom. The reaction with chloride-containing Pd(II) complexes does not lead to C-H activation but to coordination complexes without Pd-C bonds. Cycloplatination of 1,3-di-(2-pyridyl)benzene takes place at C-2 of the benzene ring, generating a terdentate ligand. This behavior is the same as that previously observed for Ru and Os. Both orthometalated complexes have been structurally characterized by X-ray diffraction.

  DOI：

  10.1021/om990125g