1,2-dimethyldisilane-bis(1,2-dicyclopentadienyl-titandimethyl) | 329774-60-9

• 英文名称: 1,2-dimethyldisilane-bis(1,2-dicyclopentadienyl-titandimethyl)
• 英文别名: 1,2-Dimethyldisilan-bis(dicyclopentadienyl-titandimethyl)
• CAS: 329774-60-9
• 化学式: C₂₆H₃₄Si₂Ti₂
• 分子量: 498.487
• InChiKey: RCBOSQHYEWWEOV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,2-dimethyldisilane-bis(1,2-dicyclopentadienyl-titandichloride) 、 甲基锂 以 乙醚 、 甲苯 、 正戊烷 为溶剂， 以89%的产率得到1,2-dimethyldisilane-bis(1,2-dicyclopentadienyl-titandimethyl)
  参考文献：
  名称：

  Synthese verbrückter binuklearer Titanocenverbindungen - Kristallstruktur von Cl2Ti[(C5H4)(C5H4)(Me)Si-Si(Me)(C5H4)(C5H4)]TiCl2 · PhMe

  摘要：

  Starting from Cp-2(Me)Si-Si(Me)Cp-2 1 the complexes X2Ti[(C5H4)(C5H4)(Me)Si-Si(Me)(C5H4)(C5H4)]TiX2 (X = Cl (2a); X - Me (3)) were synthesized. The compounds were characterized by means of their H-1- and C-13-n.m.r. and MS-spectra. The crystal structure of 2a . PhMe was determined.

  DOI：

  10.1002/1521-3749(200101)627:1<28::aid-zaac28>3.0.co;2-r