[(C5Me5)Ru(η5-pentalenyl)] | 330207-56-2

• 英文名称: [(C5Me5)Ru(η5-pentalenyl)]
• CAS: 330207-56-2
• 化学式: C₁₈H₂₂Ru
• 分子量: 339.443
• InChiKey: YRLCIDVCZJCDTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 [(C5Me5)Ru(η5-pentalenyl)] 在 n-C₄H₉Li 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以46%的产率得到[(η5-pentamethylcyclopentadienyl)Ru(μ-η5,η3-C8H6)Rh(η4-1,5-cyclooctadiene)]
  参考文献：
  名称：

  A New Heterobimetallic Ru,Rh Complex with a Dianionic Pentalene as Bridging Ligand. Synthesis, Crystal Structure, and Catalytic Activity of [Cp*Ru(μ-η⁵,η³-C₈H₆)Rh(η⁴-COD)]

  摘要：

  The heterobimetallic complex [Cp*Ru(mu-eta (5),eta (3)-C8H6)Rh(eta (4)-COD)] (2) is synthesized and characterized spectroscopically and structurally. The structure of this compound exhibits the two metal centers bonded in an anti disposition to the pentalenyl ligand. The displacement of the coordinated COD by carbon monoxide is studied. The bimetallic complex shows a high activity and selectivity for the dehydrogenative silylation of styrene.

  DOI：

  10.1021/om000941k