ZrCl3(qamph) | 1350744-59-0

• 英文名称: ZrCl3(qamph)
• 英文别名: (2-tert-butyl-6-[(quinolin-8-ylamino)methyl]phenolato)trichlorozirconium(IV)
• CAS: 1350744-59-0
• 化学式: C₂₀H₂₁Cl₃N₂OZr
• 分子量: 502.983
• InChiKey: USCRJQJLYVJUSQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zirconium tetrachloride bis(tetrahydrofuran) complex 、 2-tert-butyl-6-[(quinolin-8-ylamino)methyl]phenol 在 potassium tert-butoxide 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到ZrCl3(qamph)
  参考文献：
  名称：

  Synthesis and olefin polymerization activity of (quinolin-8-ylamino)phenolate and (quinolin-8-ylamido)phenolate Group 4 metal complexes

  摘要：

  New Zr and Hf complexes bearing either a tridentate monoanionic 2-tert-butyl-6-[(quinolin-8-ylamino) methyl]phenolate [N,N,O-] or a dianionic 2-tert-butyl-6-[(quinolin-8 ylamido)methyl]phenolate [N,N-,O-] ligand have been synthesized and characterized. The geometries of the zirconium complexes have been studied using DFT methods. The complexes were tested as catalysts in the polymerization of ethylene and alpha-olefins after activation with methylalumoxane, resulting in the production, with moderate activities, of high molecular weight linear polyethylene and prevailingly isotactic polypropylene, poly(1-butene), poly(1-pentene) and poly(1-hexene). The content of isotactic pentads of these poly(alpha-olefins) increases while the size of the monomer increases, ranging between 50% for polypropylene and 99% for poly(1-hexene). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2011.09.023