Ru3(μ-H)2(μ3-PMe2C10H5)(μ-bis(diphenylphosphino)methane)(CO)6 | 848151-16-6

• 英文名称: Ru3(μ-H)2(μ3-PMe2C10H5)(μ-bis(diphenylphosphino)methane)(CO)6
• CAS: 848151-16-6
• 化学式: C₄₃H₃₅O₆P₃Ru₃
• 分子量: 1043.88
• InChiKey: MGEGDADOVXQBOI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Ru3(μ-bis(diphenylphosphino)methane)(CO)9(PMe2(naphthyl)) 以 四氢呋喃 为溶剂， 以86%的产率得到Ru3(μ-H)2(μ3-PMe2C10H5)(μ-bis(diphenylphosphino)methane)(CO)6
  参考文献：
  名称：

  Ruthenium carbonyl clusters containing PMe2(nap) and derived ligands (nap=1-naphthyl): generation of naphthalyne derivatives

  摘要：

  Bis(dimethylphosphino)naphthalene, 1,8-(PMe2)(2)C10H6 (dmpn), reacts readily with Ru-3(CO)(12) or Ru-3(mu-dppm)(CO)(10) with replacement of one of the PMe2 groups by H to give Ru-3(CO)(12-n){PMe2(nap)}n (n = 1 2, 2 3) or Ru-3(mu-dppm)(CO)(9){PMe2(nap)} 4; the complex Ru-3(CO)(10)(dmpn) 1 is obtained only in small amount. Thermolysis of 2 or 4 gives Ru-3(mu-H)(2){mu(3)-PMe2(C10H5)}(mu-dppm)(n)(CO)(8-2n) (n = 0 5, 1 6, respectively) containing mu(3)-naphthalyne groups. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.085