| 1006388-69-7

• CAS: 1006388-69-7
• 化学式: C₁₇H₂₄ClN₂PdRu*F₆P
• 分子量: 644.298
• InChiKey: SHZOKHBLMNKZSS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate 、 chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) 以 二氯甲烷 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  η⁶-Coordination of a Ruthenium(II) Organometallic Fragment to the Arene Ring of N,C,N-Pincer Metal Complexes

  摘要：

  Stable heterobimetallic complexes of the type [MX(NCN)Ru(C5R5)](+) (R = H or Me), where the phenylene ring of an NCN-pincer ligand coordinates first to a-platinum or palladium center via a a-bond, and second to a ruthenium organometallic fragment via a g-bond, are synthesized in a single step involving electrophilic attack of a cationic Ru species on the aryl metal complex. X-ray crystal structures and solution NMR agree on the simultaneous presence of orthogonal eta(6) - and eta(1)-coordination axes. Pt-195 NMR and electrochemistry show that the eta(6)-coordinated ruthenium fragment has a strong electron-withdrawing effect on the pincer metal, which leads to a diminished nucleophilicity of the platinum center toward electrophiles such as SO2.

  DOI：

  10.1021/om7009649