| 206656-15-7

• CAS: 206656-15-7
• 化学式: C₂₂H₂₂NO₇Re
• 分子量: 598.626
• InChiKey: RCUNJTMITKCTJK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (NEt4)2[rhenium(I)(bromide)3(carbonyl)3] 、 Boc-Phe-O- 在 (polymer)-p-C₆H₄(C₆H₅)2P=N-N=C(CH)4 作用下， 以 乙腈 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  A Polymer-Supported Phosphazine as a Stable and Practical Reagent in the Three-Component Synthesis of Substituted (Cyclopentadienyl)tricarbonylrhenium Complexes

  摘要：

  A very stable heterogenized difunctional cyclopentadienyl-ring precursor, storable under ambient conditions, readily participates in the simultaneous formation of a η5 bond with a [fac-Re(CO)3 ]+ species and a σ bond with heteroatom (halides, carboxylates) or carbon nucleophiles (boronic acids) to produce halo-, acyloxy-, or carbon-substituted cyclopentadienyl-Re(CO)3 complexes in a one-pot reaction in yields of between 41 and 71 % [Eq. (1)]. No catalyst is required and unprotected (usually) sensitive functional groups are well tolerated.

  DOI：

  10.1002/(sici)1521-3773(19990601)38:11<1617::aid-anie1617>3.0.co;2-z