silver(I) bis[α-(4-pyridyl)benzhydrol] triflate acetonitrile | 798547-25-8

• 英文名称: silver(I) bis[α-(4-pyridyl)benzhydrol] triflate acetonitrile
• CAS: 798547-25-8
• 化学式: C₃₉H₃₃AgF₃N₃O₅S
• 分子量: 820.638
• InChiKey: YHARPFSXIVVEDE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯基(4-吡啶基)甲醇 、 silver trifluoromethanesulfonate 、 乙腈 以 四氢呋喃 、 乙腈 为溶剂， 以72%的产率得到silver(I) bis[α-(4-pyridyl)benzhydrol] triflate acetonitrile
  参考文献：
  名称：

  The Structural Role of the Triflate Anion in the Non‐Covalent Silver Polymer [Ag(LOH) ₂ (CF ₃ SO ₃ )(CH ₃ CN)] {LOH = α‐(4‐Pyridyl)benzhydrol}

  摘要：

  AbstractAg(CF3SO3) was reacted with the ligand α‐(4‐pyridyl)benzhydrol (LOH) in order to build a mixed organic/inorganic analogue of wheel‐and‐axle diols. In the resulting [Ag(LOH)2(CF3SO3)(CH3CN)] complex, the metal is four‐coordinate, with two pyridines trans each other and a triflate and an acetonitrile group completing a sawhorse geometry. The main structural motif is based on the strongest and most directional tectons, the coordination bond Ag−O and the hydrogen bonds −OH···O−S−O···HO−. Secondly, the sixfold phenyl embrace, CH3···π, CH3···CF3 and Ag···F tectons also direct the crystal assembly. A new synthon originating from the combination of the S−O···HO−, the π···CH3 and the CH3···CF3 individual tectons is identified. The structural roles of the anion and of the solvent are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200300929