| 337456-27-6

• CAS: 337456-27-6
• 化学式: C₁₆H₂₆Cl₂FeN₂Si₂Ti
• 分子量: 477.2
• InChiKey: DHCICKLJPCNZPM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 甲基锂 以 乙醚 为溶剂， 以85%的产率得到((η50C5H4NSiMe3)2Fe)TiMe2
  参考文献：
  名称：

  Silylated 1,1‘-Diaminoferrocene:  Ti and Zr Complexes of a New Chelating Diamide Ligand

  摘要：

  Silylation of 1,1 ' -diaminoferrocene afforded 1,1 ' -Fc(NHSiMe3)(2) (LH2) as red air-sensitive crystals. Reaction with M(CH2Ph)(4) (M = Ti, Zr) afforded the corresponding LM(CH2Ph)(2) (M Zr; Ti), where the Fc(NSiMe3)(2)(2-) group serves as a diamide ligand. Alternatively, the magnesium salt LMg(THF)(2) was reacted with TiCl4(THF)(2) to give LTiCl2 as purple air-sensitive crystals. Methylation of the latter with MeLi affords LTiMe2.

  DOI：

  10.1021/om0008979
• 作为产物：
  描述：

  tetrachlorobis(tetrahydrofuran)titanium(IV) 、 Fc(NSiMe3)2(magnesium)(THF)2 以 甲苯 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  Silylated 1,1‘-Diaminoferrocene:  Ti and Zr Complexes of a New Chelating Diamide Ligand

  摘要：

  Silylation of 1,1 ' -diaminoferrocene afforded 1,1 ' -Fc(NHSiMe3)(2) (LH2) as red air-sensitive crystals. Reaction with M(CH2Ph)(4) (M = Ti, Zr) afforded the corresponding LM(CH2Ph)(2) (M Zr; Ti), where the Fc(NSiMe3)(2)(2-) group serves as a diamide ligand. Alternatively, the magnesium salt LMg(THF)(2) was reacted with TiCl4(THF)(2) to give LTiCl2 as purple air-sensitive crystals. Methylation of the latter with MeLi affords LTiMe2.

  DOI：

  10.1021/om0008979