| 909406-71-9

• CAS: 909406-71-9
• 化学式: C₃H₆O*C₁₇H₁₃Cl₃N₂O₅SnW
• 分子量: 792.3
• InChiKey: VNMMDPWDMQUICN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 4-羟基苯甲酰肼 、 丙酮 以 乙醇 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  New pentacoordinate bicyclodiazastannsulfide formed between the functionalized cyclopentadienyl ring and tin

  摘要：

  New pentacoordinate bicyclodiazastannsulfide fused cyclopentadienyl M-Sn (M = Mo or W) bonded organometallic heterocycle {mu-[C5H4(CH3)C=N-N=C(S)Ar]M(CO)(3)SnCl2} has been obtained by the condensation reaction of CH3COC5H4M(CO)(3)SnCl3 with arylthiocarboxyhydrazide (ArCSNHNH2, Ar = 2-furanyl, 2-thienyl, 2- or 4-hydroxyphenyl) in mild conditions. While the similar reaction of CH3COC5H4M(CO)(3)SnCl3 with ArCONHNH2 (Ar = 2- or 4-hydroxyphenyl) only gives non-cyclic compounds [C5H4(CH3)C=N-NHC(O)Ar]M(CO)(3)SnCl3, in which the tin atom remains tetracoordinate. In bicyclodiazastannsulfide the tin atom prefers to adopt pentacoordinate geometry, while in the corresponding bicyclodiazastannoxide the tin atom is hexacoordinate. In addition, phenylhydrazine, 2- or 4-hydroxyphenylcarboxyhydrazide is used to react with CH3COC5H4M(CO)(3)SnCl3, only tetracoordinate non-cyclic tin compound is obtained. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.05.010