((η6-p-cymene)Ru(2,2'-dipyridyl-N-methylimine)Cl)(hexafluorophosphate) | 1265678-74-7

• 英文名称: ((η6-p-cymene)Ru(2,2'-dipyridyl-N-methylimine)Cl)(hexafluorophosphate)
• CAS: 1265678-74-7
• 化学式: C₂₂H₂₅ClN₃Ru*F₆P
• 分子量: 612.948
• InChiKey: SGKMYZVGYLOZPH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-dipyridyl ketone N-methylimine 、 ammonium hexafluorophosphate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 以 甲醇 为溶剂， 以76%的产率得到((η6-p-cymene)Ru(2,2'-dipyridyl-N-methylimine)Cl)(hexafluorophosphate)
  参考文献：
  名称：

  Synthesis, spectral and structural studies of water soluble arene ruthenium (II) complexes containing 2,2′-dipyridyl-N-alkylimine ligand

  摘要：

  A series of water soluble complexes of general formula [(eta(6)-arene)Ru {(C5H4N)(2)CNRi}Cl]PF6 have been prepared by the reaction of [{(eta(6)-arene)RuCl2}(2)] with appropriate 2,2'-dipyridyl-N-alkylimine ligands (dpNRi) in the presence of NH4PF6 (where; R = Me or Et; arene = p-cymene, C6Me6, C6H6). The 2,2'-dipyridyl-N-alkylimine ligands are prepared by reaction of 2,2'-dipyridyl ketone with the corresponding alkylamine. The complexes are readily obtained as air stable yellow to dark brown solids by simple stirring at room temperature. The complexes are isolated as their hexafluorophosphate salts and characterized on the basis of spectroscopic data. The molecular structure of representative complex [(eta(6)-C6Me6)Ru{(C5H4N)(2)C=N-Me}Cl]PF6 has been determined by single crystal X-ray diffraction studies. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.09.037