(η3-C3H5)Pd(μ-SC6H4F-4)2Pd(η3-C3H5) | 609844-86-2

• 英文名称: (η3-C3H5)Pd(μ-SC6H4F-4)2Pd(η3-C3H5)
• CAS: 609844-86-2
• 化学式: C₁₈H₁₈F₂Pd₂S₂
• 分子量: 549.31
• InChiKey: WSPRLYJTYJAVCM-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 lead (SC6H4-4-F)2 以 丙酮 为溶剂， 以97%的产率得到(η3-C3H5)Pd(μ-SC6H4F-4)2Pd(η3-C3H5)
  参考文献：
  名称：

  Allyl–palladium compounds with fluorinated benzenethiolate ligands. X-ray crystal structure of [(η3-C3H5)Pd(μ-SC6H4F-4)2Pd(η3-C3H5)]

  摘要：

  Treatment of the di-lt-chloride allyl-palladium complex [(eta (3)-C3H5)Pd(mu -Cl)(2)Pd(eta (3)-C3H5)] with Pb(SR)(2) in acetone affords dinuclear fluorothiolate bridged complexes of the type [(eta (3)-C3H5)Pd(mu -SR)(2)Pd(eta (3)-C3H5)] (R = C6F5, 1; C6HF4-4, 2: C6H4F-2, 3; C6H4F-3, 4 and C6H4F-4, 5). Complex 1 reacts with pares-substituted phosphines P(C6H4X-4)(3) to give the mononuclear perfluorobenzenethiolate complexes [Pd(SC6F5)(eta (3)-C3H5)(P(C6H4X-4)(3))] (X = F, 6; CF3, 7; OCH3, 8 and CH3, 9). The single crystal X-ray diffraction structure of [(eta (3)-C3H5)Pd(mu -SC6H4F-4)(2)Pd(eta (3)-C3H5)] (5) has been resolved. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(01)00934-2