| 12026-56-1

• CAS: 12026-56-1
• 化学式: H₃Sr*Li
• 分子量: 97.5848
• InChiKey: NDLSENLOCWDZNM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  lithium amide 、 strontium(II) hydride 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and crystal structure of a novel nitride hydride Sr2LiNH2

  摘要：

  The novel nitride hydride Sr2LiNH2 was synthesized by dehydrogenating a LiNH2 + 2SrH(2) mixture at about 330 degrees C. It was found that Sr2LiNH2 crystallizes with a tetragonal structure in space group 14/mmm (no. 139), and with cell parameters: a = b= 3.8104(4)angstrom and c= 13.722(1)angstrom. The crystal structure of Sr2LiNH2 can be described as a stacking of [Sr5Li] octahedra, which is different from those of nitride hydrides of lithium (Li4NH) and strontium (Sr2NH) as well as ternary imides (e.g. Li2Mg(NH)(2) and Li2Ca(NH)(2)). (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2010.02.011