| 504398-76-9

• CAS: 504398-76-9；504398-73-6
• 化学式: C₂₅H₁₈N₂O₁₀P₂W₂
• 分子量: 936.073
• InChiKey: RGIBXBDNZWRMGZ-SARYEQCUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  carbon monoxide;phenyl(phenylphosphanylidene)phosphane;tungsten 、 二甲基氢胺 以 xylene 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Reaction of a Diphosphene Complex with Dimethylcyanamide

  摘要：

  The reaction of the diphenyldiphosphene[W(CO)(5)](3) complex 1 with N,N-dimethylcyanamide affords complex 2, resulting from the formal addition of one H and one N=CH-NMe2 unit onto the P=P double bond of 1 as the major product. A bicyclic complex (3) probably resulting from an initial substitution of one cis-CO of each [P- W(CO)(5)] group by the cyanamide is also formed. Both 2 and 3 have been characterized by X-ray crystal structure analysis.

  DOI：

  10.1021/om021016w