TiCl4(THF-d8)2 | 952116-56-2

• 英文名称: TiCl4(THF-d8)2
• CAS: 952116-56-2
• 化学式: C₈H₁₆Cl₄O₂Ti
• 分子量: 349.779
• InChiKey: LXWBMENBONGPSB-WSRCOECHSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氘代四氢呋喃 、 (E)-[Me(Me3Si)3SiSiO]2Ti2Cl6 以 氘代四氢呋喃 为溶剂， 生成 TiCl4(THF-d8)2
  参考文献：
  名称：

  Synthesis and structure of titanium and zirconium disilane-1,2-diolates

  摘要：

  The synthesis and structure of zirconium and titanium complexes containing the chelating disilane-1,2-diolate ligand rac-[Me(Me3Si)(3)SiSiO](2)(2-) (1)-2H are reported. The compounds (E)-[Me(Me3Si)(3)SiSiO](2)TiCl2 (3a) and (E)-[Me(Me3Si)(3)SiSiO](2)Zr-Cl2 center dot THF (3b) were prepared by the reactions of MCl4 (M=Ti, Zr) with {(E)-[Me(Me3Si)(3)SiSiO](2)}(2)Ti(2a) and {(E)-[Me(Me3Si)(3)SiSiO](2)Zr center dot HNEt2 (2b), which are derived from the reaction of 1 with Zr(NEt2)(4) and Ti(OEt2)(4), respectively. Upon treatment with 3 equiv. of TiCl4, 2a undergoes a ring opening reaction to yield the dinuclear complexes (E)-[Me(Me3Si)(3)SiSiO](2)Ti2Cl6 (4) and (E)-[MC(Me3Si)(3)SiSiO](2)Ti2OCl4 (5). The solid state structures of 2a, 5 and TiCl4-2THF-d(8) have been determined by X-ray crystallography. (c) 2007 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2007.03.043