[Cu(4-hydroxysalicylidene-2-aminopyrimidine-H)Cl(H2O)]*H2O | 1235393-14-2

• 英文名称: [Cu(4-hydroxysalicylidene-2-aminopyrimidine-H)Cl(H2O)]*H2O
• CAS: 1235393-14-2
• 化学式: C₁₁H₁₀ClCuN₃O₃*H₂O
• 分子量: 349.233
• InChiKey: VNILSUSTUJAWDU-IJAVRYICSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-hydroxysalicylidene-2-aminopyrimidine 、 水 、 copper dichloride 以 乙醇 为溶剂， 生成 [Cu(4-hydroxysalicylidene-2-aminopyrimidine-H)Cl(H2O)]*H2O
  参考文献：
  名称：

  pH-metric and spectroscopic properties of new 4-hydroxysalicylidene-2-aminopyrimidine Schiff-base transition metal complexes

  摘要：

  The new complexes, cis-[WO2(Hsap)(2)], [Ru(PPh3)(2)(Hsap)(2)], [Pd(Hsap)Cl(H2O)], [Pd(PPh3)(2)(Hsap)]Cl, [Ag(Hsap)(H2O)(2)], [Ni(Hsap)(AcO)(H2O)(2)]. [Ni(Hsap)(2)] and [Cu(Hsap)Cl(H2O)] are reported, where H(2)sap is 4-hydroxysalicylidene-2-amino pyrimidine Schiff-base. The complexes were characterized by elemental analyses, spectroscopic (IR, NMR, UV-vis, ESR and mass) and physical techniques (conductivity, magnetic and thermal measurements). The Schiff-base H(2)sap behaves as a bidentate chelate with the deprotonated 2-hydroxy and azomethine nitrogen centers with the pendant pyrimidine cyclic nitrogen functionality playing no role in coordination. The dissociation constants of H(2)sap and the stability constants of the metal complexes have been determined pH-metrically at various temperatures, and the thermodynamic activation parameters (Delta S*, Delta G*, Delta N*) calculated. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2010.03.037