iodine-argon comlex | 67708-07-0

• 英文名称: iodine-argon comlex
• CAS: 67708-07-0
• 化学式: Ar*I₂
• 分子量: 293.757
• InChiKey: AKUQTDYSNRGPIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.77
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氩 、 碘 以 gaseous matrix 、 solid 为溶剂， 生成 iodine-argon comlex
  参考文献：
  名称：

  I2(B)-Ar 的解离动力学：来自 T 形和线性配合物的 I2(B,v) 片段的旋转种群分布

  摘要：

  光学-光学双共振技术已被用于检查 I2(B)-Ar 的解离动力学。对 I2(B,v) 片段的旋转种群分布进行了表征。T 形复合物的振动预解离产生具有平滑旋转分布的碎片。分布的高能量限制与将几乎所有可用能量引导到产品旋转的事件一致。这些数据表明 I2(B)-Ar 的解离能为 D0(C2v)=220 cm-1。复杂的大多数初始状态产生双峰旋转种群分布，但少数给出玻尔兹曼型乘积分布。分布特征对初始激发态的依赖性表明预解离是由分子内振动能量再分配介导的。线性 I2(B)-Ar 的解离产生具有玻尔兹曼型旋转种群分布的片段。B-X 跃迁的结合区域内复合物的激发...

  DOI：

  10.1063/1.1359771

文献信息

• Dynamics of linear and T-shaped Ar–I2 dissociation upon B←X optical excitation: A dispersed fluorescence study of the linear isomer
  作者：Amy E. Stevens Miller、Cheng-Chi Chuang、Henry C. Fu、Kelly J. Higgins、William Klemperer

  DOI：10.1063/1.480120

  日期：1999.11

  We report the dispersed fluorescence spectra of the linear and the previously well-studied T-shaped isomers of Ar–I2 following B←X optical excitation for vpump=16–26, below the I2 dissociation limit. The linear isomer has a continuum excitation spectrum. For excitation at the highest pumping energy (vpump=26), the product vibrational state distribution is nearly identical to that observed for excitation above the I2(B) dissociation limit; it shows a broad, nearly Gaussian distribution of I2(B) vibrational states, with about 22% of the available excess energy deposited in translation of the Ar+I2. This gives direct evidence that the “one-atom cage” effect seen above the I2(B) dissociation limit is attributable to the linear Ar–I2 isomer. The product vibrational state distribution becomes increasingly Poisson for decreasing excitation energies, and only about 7% of the excess energy is deposited in translation for vpump=16. The bond energy in the linear isomer is determined from the spectra, 170(±1.5)⩽D0″(linear Ar–I2(X))⩽174(±1.5) cm−1. A bond energy of D0″(T-shaped Ar–I2(X))=142±15 cm−1 is estimated based on the linear to T-shaped population ratio observed in the beam, which is about 90 cm−1 smaller than that determined from fluorescence spectra. We suggest that electronic quenching in the T-shaped isomer is nearly 100% for the highest vibrational level produced by vibrational predissociation.
• Product vibrational state distributions in the photodissociation of iodine - rare gas clusters
  作者：J. M. Philippoz、H. Van den Bergh、R. Monot

  DOI：10.1021/j100294a020

  日期：1987.5