(3,5-Me2C6H3N(1-adamantyl))3NbCl | 215254-46-9

• 英文名称: (3,5-Me2C6H3N(1-adamantyl))3NbCl
• CAS: 215254-46-9
• 化学式: C₅₄H₇₂ClN₃Nb
• 分子量: 891.545
• InChiKey: VWSWPMNQDZWRHQ-XBSDIDAQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 (3,5-Me2C6H3N(1-adamantyl))3NbCl 在 neophyl lithium 作用下， 以 四氢呋喃 为溶剂， 以31%的产率得到(3,5-Me2C6H3N(1-adamantyl))3Nb(OCH=CH2)
  参考文献：
  名称：

  Tetravalent niobium alkyls and enolate stabilized by anionic organic amides

  摘要：

  The lithium amide [3,5-Me2PhN(Ad)]Li . Et2O reacts with NbCl4(THF)(2) to give [3,5-Me2PhN(Ad)](3)NbCl (1). Reactions of 1 with PhLi and MeLi produced the corresponding alkyl derivatives [3,5-Me2PhN(Ad)](3)NbR (R= Ph (2a), Me (2b)). Attempts to prepare a neophyl niobium derivative led instead to the formation of the corresponding enolate [ 3,5-Me2PhN(Ad)](3)Nb(OCH=CH2) (3), arising from the cleavage of THF. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00059-0
• 作为产物：
  描述：

  NbCl₄(THF)₂ 、 以 乙醚 为溶剂， 以53%的产率得到(3,5-Me2C6H3N(1-adamantyl))3NbCl
  参考文献：
  名称：

  Tetravalent niobium alkyls and enolate stabilized by anionic organic amides

  摘要：

  The lithium amide [3,5-Me2PhN(Ad)]Li . Et2O reacts with NbCl4(THF)(2) to give [3,5-Me2PhN(Ad)](3)NbCl (1). Reactions of 1 with PhLi and MeLi produced the corresponding alkyl derivatives [3,5-Me2PhN(Ad)](3)NbR (R= Ph (2a), Me (2b)). Attempts to prepare a neophyl niobium derivative led instead to the formation of the corresponding enolate [ 3,5-Me2PhN(Ad)](3)Nb(OCH=CH2) (3), arising from the cleavage of THF. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00059-0