| 149613-35-4

• CAS: 149613-35-4
• 化学式: C₁₃H₂₃Cl₂NRu
• 分子量: 365.308
• InChiKey: YQKYAPJGILCWAO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(mesitylene)ruthenium(II) dimer 、 二乙胺 以 氯仿 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Reactions of amines with arene-ruthenium complexes: crystal structures of [(1,3,5-Me3C6H3) RuCl2(HNC5H10)] and [(1,3,5-Me3C6H3)RuCl2(NC5H5)]

  摘要：

  A range of primary and secondary amines have been reacted with the dimers [(arene)RuCl2]2 to give simple adducts [(arene)RuCl2(NHRR1)]. We have structurally characterized the complexes [(1,3,5-Me3C6H3)RuCl2(HNC5H10)] and [(1,3,5-Me3C6H3) RuCl2(NC5H5)]. Amine exchange reactions have been performed to assess the relative stabilities of these adducts. With certain ligands complex cations, [(1,3,5-Me3C6H3)RuCl (NHRR1)2]+, can form, although these are more easily prepared by reaction in the presence of AgBF4.

  DOI：

  10.1016/s0277-5387(00)88200-5