1-acetyl-2-(chloromercuri)ferrocene | 85356-65-6

• 英文名称: 1-acetyl-2-(chloromercuri)ferrocene
• 英文别名: 2-(chloromercuri)-1-acylferrocene
• CAS: 85356-65-6
• 化学式: C₁₂H₁₁ClFeHgO
• 分子量: 463.109
• InChiKey: XXMHHOVIGLCGSC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2-氨基吡啶 、 1-acetyl-2-(chloromercuri)ferrocene 在 aluminum oxide 作用下， 以 四氢呋喃 为溶剂， 以40%的产率得到2-chloromercurio-1-[(pyridyl-2-imino)ethyl]ferrocene
  参考文献：
  名称：

  Studies on the synthesis and structural characterization of cyclomercurated ferrocenylimines containing heterocyclic ring

  摘要：

  The cyclomercurated ferrocenylimines containing heterocyclic ring can be prepared by the cyclomercuration of acylferrocene, followed by the condensation of the resulting product with the appropriate heterocyclic amine. This procedure provides an efficient method for the synthesis of cyclomerucurated ferrocenylimines containing heterocyclic ring which is difficultly synthesized by the traditional method, i.e. imination and then cyclomercuration. A series of these compounds were synthesized by this new method and characterized. The X-ray crystal structure of [HgCl(eta(5)-C5H3C(CH3)=N-2-C5H3N-6-CH3) Fe(eta(5)-C5H5)] (3d) has been determined and the reaction mechanism was proposed. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01810-7

文献信息

• Electron transfer in organometallic clusters. 2. Ferrocene-tricobalt carbon cluster compounds with multiple redox sites
  作者：Stephen B. Colbran、Brian H. Robinson、Jim Simpson

  DOI：10.1021/om50002a001

  日期：1983.8