[Ti(adamantanoxo)2Cl2(thf)2] | 904293-77-2

• 英文名称: [Ti(adamantanoxo)2Cl2(thf)2]
• CAS: 904293-77-2
• 化学式: C₂₈H₄₆Cl₂O₄Ti
• 分子量: 565.457
• InChiKey: BOSACLOGUOHSIU-NGSSYPTOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrachlorobis(tetrahydrofuran)titanium(IV) 、 tetrakis(adamantanoxy) titanium(IV) 以 四氢呋喃 为溶剂， 以69%的产率得到[Ti(adamantanoxo)2Cl2(thf)2]
  参考文献：
  名称：

  Polymerization of ε-caprolactone using bulky alkoxo-titanium complexes and structural analysis of [Ti(OBorneoxo)2Cl2(thf)2]

  摘要：

  A variety of bisalkoxo titanium dichloride THF adducts [Ti(OR)(2)Cl-2(thf)(2)] {OR = adamantanoxo (9), (1R,2S,5R)-(-)-menthoxo (10), (1S-endo)-(-)-borneoxo (11)} have been prepared and characterized by spectroscopic techniques. The molecular structure of It has been determined by single-crystal X-ray diffraction studies. The parent Lewis acid bisalkoxo titanium dichloride derivatives and related alkoxo complexes [Ti(OR)(2)(OPri)(2)](2) have been tested as initiators in ring-opening polymerization of epsilon-caprolactone and L-lactide. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.03.019