| 136921-41-0

• CAS: 136921-41-0
• 化学式: C₁₃H₁₆CrN₂O₇S₂
• 分子量: 428.407
• InChiKey: GUIHIDZUZCHRRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 、 乙腈 以 乙腈 为溶剂， 生成 tetrakis(acetonitrile)copper(I) perchlorate
  参考文献：
  名称：

  Redox and coordinative properties of N,N′-dithiobisamines: Oxidative desulphurization by copper(II) ions and Cr(CO)5[S2(NR2)2] complexes

  摘要：

  N,N'-dithiobisamines, R2N-S-S-NR2, NR2 = N(CH3)2, N(CH2CH3)2,[GRAPHICS]or N(CH2-C6H5)2, are oxidized to SO2 by copper(II) salts with formation of copper(I) complexes, while from the reaction with pentacarbonyl (tetrahydrofuran)chromium the novel complexes Cr(CO)5[S2(NR2)2] were isolated. They have been characterized by elemental analysis as well as by spectroscopic methods. The pi-acceptor abilities of the sulphur-containing ligands in the Cr(CO5)L complexes are discussed and compared with those found for their analogous monothio derivatives. Reactivity of the coordinated sulphur compounds towards acids and copper(II) salts is less than that of the free ligands.

  DOI：

  10.1016/s0277-5387(00)81264-4
• 作为产物：
  描述：

  促进剂 DTDM 、 六羰基铬 以 四氢呋喃 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Redox and coordinative properties of N,N′-dithiobisamines: Oxidative desulphurization by copper(II) ions and Cr(CO)5[S2(NR2)2] complexes

  摘要：

  N,N'-dithiobisamines, R2N-S-S-NR2, NR2 = N(CH3)2, N(CH2CH3)2,[GRAPHICS]or N(CH2-C6H5)2, are oxidized to SO2 by copper(II) salts with formation of copper(I) complexes, while from the reaction with pentacarbonyl (tetrahydrofuran)chromium the novel complexes Cr(CO)5[S2(NR2)2] were isolated. They have been characterized by elemental analysis as well as by spectroscopic methods. The pi-acceptor abilities of the sulphur-containing ligands in the Cr(CO5)L complexes are discussed and compared with those found for their analogous monothio derivatives. Reactivity of the coordinated sulphur compounds towards acids and copper(II) salts is less than that of the free ligands.

  DOI：

  10.1016/s0277-5387(00)81264-4