| 174837-96-8

• CAS: 174837-96-8
• 化学式: C₂₆H₁₂O₈Ru₃
• 分子量: 755.586
• InChiKey: MXYKJWYLZJBSOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 diazoindene 以0%的产率得到
  参考文献：
  名称：

  Synthesis and Molecular Structure of Two Six-Membered Ru₃C₃ Rings Existing in Boat- and Chairlike Configurations Formed by Insertion of C₉H₆ Units into Metal−Metal Bonds of [Ru₃(CO)₁₂]

  摘要：

  The reaction of diazoindene (C9H6N2) with [Ru-3(CO)(12)] in THF leads to the formation of the clusters [Ru-3(CO)(10)(eta(5):eta(1)-C9H6)] (1), by the insertion of a C9H6 moiety into a Ru-Ru bond, [Ru-3(CO)(8)(eta(5)-C9H6)(2)] (2), a trinuclear complex with an open Ru-3 unit containing the 1,1'-bis(indenylidene) ligand, and two metallacyclic ruthenium trimers of formula [Ru-3(CO)(6)-(eta(5):eta(1)-C9H6)(3)] (3 and 4). The cyclic trimers have stable chair- and twist-boat-like configurations similar to the boat-chair isomerism of cyclohexane. Both complexes are configurational rather than conformational isomers, because the boat-to-chair ring flip is hampered by the rigid nature of the Ru3C3 metallacycle. The structures of 2-4 have been established by X-ray crystallography.

  DOI：

  10.1021/om9600102
• 作为产物：
  描述：

  十二羰基三钌 、 dibenzopentafulvalen 以 四氢呋喃 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Synthesis and Molecular Structure of Two Six-Membered Ru₃C₃ Rings Existing in Boat- and Chairlike Configurations Formed by Insertion of C₉H₆ Units into Metal−Metal Bonds of [Ru₃(CO)₁₂]

  摘要：

  The reaction of diazoindene (C9H6N2) with [Ru-3(CO)(12)] in THF leads to the formation of the clusters [Ru-3(CO)(10)(eta(5):eta(1)-C9H6)] (1), by the insertion of a C9H6 moiety into a Ru-Ru bond, [Ru-3(CO)(8)(eta(5)-C9H6)(2)] (2), a trinuclear complex with an open Ru-3 unit containing the 1,1'-bis(indenylidene) ligand, and two metallacyclic ruthenium trimers of formula [Ru-3(CO)(6)-(eta(5):eta(1)-C9H6)(3)] (3 and 4). The cyclic trimers have stable chair- and twist-boat-like configurations similar to the boat-chair isomerism of cyclohexane. Both complexes are configurational rather than conformational isomers, because the boat-to-chair ring flip is hampered by the rigid nature of the Ru3C3 metallacycle. The structures of 2-4 have been established by X-ray crystallography.

  DOI：

  10.1021/om9600102