RuCl2[2-(diphenylphosphinomethyl)aniline]2 | 1357295-49-8

• 英文名称: RuCl2[2-(diphenylphosphinomethyl)aniline]2
• CAS: 1357295-49-8
• 化学式: C₃₈H₃₆Cl₂N₂P₂Ru
• 分子量: 754.641
• InChiKey: NWZQJKPFUDZZEL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 2-(diphenylphosphinomethyl)aniline 以 二氯甲烷 为溶剂， 生成 RuCl2[2-(diphenylphosphinomethyl)aniline]2
  参考文献：
  名称：

  Ruthenium(II) complexes with 2-(diphenylphosphinomethyl)aniline

  摘要：

  2-(Diphenylphosphinomethyl)aniline. H2L1, reacts with [RuCl2(PPh3)(3)] to yield the monomeric complexes [RuCl2(H2L1)(PPh3)(CH3CN)], [RuCl2(H2L1)(2)]and the chloro-bridged dimer [(H2L1)(PPh3)Ru(mu-Cl)(2)Ru(PPh3) (H2L1)] depending on the conditions applied. Exclusively the monochelate [RuCl2 (H2L1)(dmso)(2)] is formed during reactions of H2L1 with [RuCl2(dmso)(4)]. H2L1 acts as a neutral, bidentate ligand in all complexes. The products are studied spectroscopically and by X-ray diffraction. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.12.018