[Ru((Z)-HC=CHC6H4NO2)(CO)(PMe2Ph)(η5-C5Ph5)] | 850429-79-7

• 英文名称: [Ru((Z)-HC=CHC6H4NO2)(CO)(PMe2Ph)(η5-C5Ph5)]
• CAS: 850429-79-7
• 化学式: C₅₂H₄₂NO₃PRu
• 分子量: 860.954
• InChiKey: GBAYLXUBQLNPLB-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Ru((Z)-HC=CHC6H4NO2)(CO)2(η5-C5Ph5)] 、 二甲基苯基磷 在 Me₃NO 作用下， 以 四氢呋喃 为溶剂， 以64%的产率得到[Ru((Z)-HC=CHC6H4NO2)(CO)(PMe2Ph)(η5-C5Ph5)]
  参考文献：
  名称：

  Synthesis and non-linear optical properties of (η5-pentaphenylcyclopentadienyl)dicarbonylruthenium(II) σ-alkenyl complexes

  摘要：

  The complexes [Ru{(Z)-HC=CHPh}(CO)(2)(eta(5)-C5Ph5)] (1) and [Ru{(Z)-HC=CHC6H4NO2}(CO)(2)(eta(5)-C5Ph5)] (2) have been synthesized and their identity confirmed by single-crystal X-ray diffraction studies. Reaction of 2 with PMe2Ph and Me3NO in tetrahydrofuran afforded [Ru{(Z)-HC=CHC6H4NO2}(CO)(PMe2Ph)(eta(5)-C5Ph5)] (3). Cyclic voltarnmetry confirms the expected increase in ease of oxidation on proceeding from 2 to 1 and from 2 to 3. Hyper-Rayleigh scattering studies at 1064 unit reveal a dramatic increase in quadratic non-linearity on co-ligand replacement of CO by PMe2Ph, in proceeding from 2 to 3. Z-scan studies at 800 nm are consistent with significant contribution from two-photon states, and with an increase in gamma(real) on co-ligand replacement of CO by PMe2Ph in proceeding from 2 to 3. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.045