[Pt(S-2-amino-2'-hydroxy-1,1'-binaphthyl)(Me2SO)Cl2] | 1261989-19-8

• 英文名称: [Pt(S-2-amino-2'-hydroxy-1,1'-binaphthyl)(Me2SO)Cl2]
• CAS: 1261989-19-8
• 化学式: C₂₂H₂₁Cl₂NO₂PtS
• 分子量: 629.466
• InChiKey: SEUMTSAETGJZFW-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  dichlorobis(dimethyl sulfoxide)platinum(II) 、 (S)-(+)-2-氨基-2'-羟基-1,1'-联萘 以 乙醇 为溶剂， 以72%的产率得到[Pt(S-2-amino-2'-hydroxy-1,1'-binaphthyl)(Me2SO)Cl2]
  参考文献：
  名称：

  Synthesis and spectral properties of mixed-ligand platinum(II) complexes with (-)-S-NOBIN and sulfoxides

  摘要：

  Synthesis was carried out of the new mixed-ligand square-planar platinum(II)complexes {Pt(R2SO)[(-)-S-NOBIN]Cl(2)}, where (-)-S-NOBIN was S-2-amino-2'-hydroxy-1,1'-binaphthyl (R = Me, Et). The complexes are of interest as catalysts for asymmetrical synthesis. The detailed analysis of NMR, UV, and CD spectra of these compounds was performed. These complexes were established to be a mixture of the corresponding cis- and trans-isomers.

  DOI：

  10.1134/s1070363210100142