[Ir(H)₂(PCy₃)₂(η²-H₃B*N^tBuH₂)][B(3,5-C₆H₃Cl₂)₄] | 1415354-49-2

• 英文名称: [Ir(H)₂(PCy₃)₂(η²-H₃B*N^tBuH₂)][B(3,5-C₆H₃Cl₂)₄]
• CAS: 1415354-49-2
• 化学式: C₂₄H₁₂BCl₈*C₄₀H₈₂BIrNP₂
• 分子量: 1436.87
• InChiKey: UGWNDZVKMQEMDV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Ir(H)₂(H₂)₂(PCy₃)₂][B(3,5-C₆H₃Cl₂)₄] 、 borane tert-butylamine 以 正戊烷 为溶剂， 反应 144.25h， 以30%的产率得到[Ir(H)₂(PCy₃)₂(η²-H₃B*N^tBuH₂)][B(3,5-C₆H₃Cl₂)₄]
  参考文献：
  名称：

  A tert-butyl-substituted amino-borane bound to an iridium fragment: A latent source of free H2BNtBuH

  摘要：

  Release of the primary amino-borane H2B=(NBuH)-Bu-t from [Ir(PCy3)(2)(H)(2)(eta(2)-H2B=(NBuH)-Bu-t)] [BAr4F], formed from dehydrogenation of [Ir(PCy3)(2)(H)(2)(eta(2)-H3B center dot(NBuH2)-Bu-t)][BAr4F], results in the eventual formation of the corresponding cyclic borazine [(HBNBu)-Bu-t](3). Observations point to the fact that off-metal hydrogen redistribution reactions play a major role in the final product formation, with H3B center dot(NBuH2)-Bu-t being formed alongside [(HBNBu)-Bu-t](3). (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.07.018