[Mn3(μ3-O)(4-OH-Me-2,4-dihydroxyacetophenone oxime)3(HCOO)(MeOH)5]·MeOH | 1426545-12-1

• 英文名称: [Mn3(μ3-O)(4-OH-Me-2,4-dihydroxyacetophenone oxime)3(HCOO)(MeOH)5]·MeOH
• CAS: 1426545-12-1
• 化学式: CH₄O*C₃₀H₄₂Mn₃N₃O₁₇
• 分子量: 913.53
• InChiKey: KKVCQJLDZIOZQP-NFEPTPIYSA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 manganese(II) perchlorate hexahydrate 、 1-(2,4-dihydroxy-phenyl)-ethanone oxime 在 sodium acetate 作用下， 反应 1.0h， 以30%的产率得到[Mn3(μ3-O)(4-OH-Me-2,4-dihydroxyacetophenone oxime)3(HCOO)(MeOH)5]·MeOH
  参考文献：
  名称：

  Structures and magnetism of two manganese crowns assembled with 2,4-dihydroxyacetophenone oxime

  摘要：

  Reactions of 2,4-dihydroxyacetophenone oxime with manganese salts yielded two manganese crowns, [Mn3( 3-O)(4-OH-Me-sao)3(HCOO)(MeOH)5]center dot MeOH (1) and [Mn3( 3-O)(4-OH-Me-sao)3(CH3COO)(MeOH)5]center dot MeOH (2) (4-OH-Me-saoH2=2,4-dihydroxyacetophenone oxime). Both compounds possess [MnIII 3( 3-O)]7+ cores which contain 9-MC-3 metallacrown (MC) rings with the repeating pattern [MnNO]. However, the difference in the structures of both compounds is coordinated carboxylates. In 1 and 2, the MC molecules are connected with each other through intermolecular hydrogen bonds, generating similar 3-D supramolecular networks. Magnetic properties reveal that in 1 and 2 the metal ions exhibit ferromagnetic exchange coupling.

  DOI：

  10.1080/00958972.2012.756103