| 1419584-55-6

• CAS: 1419584-55-6
• 化学式: C₆₀H₅₆ClFeN₆O₆
• 分子量: 1048.44
• InChiKey: DRBGLNYDMZBWCS-HGXCQNPVSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  iron(III) chloride 、 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以47.9 mg的产率得到
  参考文献：
  名称：

  Conversion of Electron Configuration of Iron Ion through Core Contraction of Porphyrin: Implications for Heme Distortion

  摘要：

  It was demonstrated experimentally that nonplanar iron porphyrins can be induced to undergo a conversion in their electronic configuration to form a cross-hybrid transition by compressing the macrocyclic core size for the central metal ion. A series of monostrapped iron porphyrins were used as model systems, and their electronic properties were probed using electron spin resonance and differential spectral analyses. These results indicate that the formation of a cross-hybrid transition stage is related to the stability of the high-valence state and potent oxidizing ability of the central iron ion.

  DOI：

  10.1021/ol303419b