[Mo(NPh)(pyridine)2(o-(Me3SiN)2C6H4)] | 360061-77-4

• 英文名称: [Mo(NPh)(pyridine)2(o-(Me3SiN)2C6H4)]
• CAS: 360061-77-4
• 化学式: C₂₈H₃₇MoN₅Si₂
• 分子量: 595.746
• InChiKey: HPGAIJMIGFHQFC-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Mo(NPh)(pyridine)2(o-(Me3SiN)2C6H4)] 以 甲苯 为溶剂， 以92%的产率得到[Mo2(NSiMe3)(NPh)2(pyridine)(o-(Me3SiN)2C6H4)(Me3SiNC6H4)]
  参考文献：
  名称：

  Unusual molybdenum mediated C–N bond activation

  摘要：

  The compounds [Mo(NPh)(η2-olefin){o-(Me3SiN) 2C6H4}] (olefin = propene 1a or isobutene 1b) react with excess pyridine affording the Mo(IV) bis-pyridine complex, [Mo(NPh)(Py)2{o-(Me3SiN)2C 6H4}] 2 which when heated to 90 °C in toluene undergoes a C–N bond cleavage reaction and is converted to 3, a bimetallic molybdenum species; the crystal structures of both 2 and 3 are reported.

  DOI：

  10.1039/b101894i
• 作为产物：
  描述：

  吡啶 、 (PhN)Mo(bis(trimethylsilyl)-o-phenylenediamide)(CH2CMe2) 以 正戊烷 为溶剂， 生成 [Mo(NPh)(pyridine)2(o-(Me3SiN)2C6H4)]
  参考文献：
  名称：

  Unusual molybdenum mediated C–N bond activation

  摘要：

  The compounds [Mo(NPh)(η2-olefin){o-(Me3SiN) 2C6H4}] (olefin = propene 1a or isobutene 1b) react with excess pyridine affording the Mo(IV) bis-pyridine complex, [Mo(NPh)(Py)2{o-(Me3SiN)2C 6H4}] 2 which when heated to 90 °C in toluene undergoes a C–N bond cleavage reaction and is converted to 3, a bimetallic molybdenum species; the crystal structures of both 2 and 3 are reported.

  DOI：

  10.1039/b101894i