摘要:
The reaction between [2-I-2-(PPh3)-closo-2,1-PdTeB10H9(PPh3)] and excess of phosphine (PR3 = PMe3 or PMe2Ph) afforded air-stable cationic palladatelluraboranes [2,2-(PR3)2-closo-2,1-PdTeB10H9(PPh3)]I 1 (PR3 = PMe3) or 2 (PR3 = PMe2Ph) which were characterised spectroscopically (IR and B-11 NMR) and by an X-ray diffraction study of 1.