[Rh(CO)(PPh3)2(3-picoline)][NO3] | 865532-84-9

• 英文名称: [Rh(CO)(PPh3)2(3-picoline)][NO3]
• CAS: 865532-84-9
• 化学式: C₄₃H₃₇NOP₂Rh*NO₃
• 分子量: 810.631
• InChiKey: YIWDUYPIYZXSDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-甲基吡啶 、 nitratocarbonylbis(triphenylphosphine)rhodium 以 further solvent(s) 为溶剂， 生成 [Rh(CO)(PPh3)2(3-picoline)][NO3]
  参考文献：
  名称：

  Promoting effect of ionic liquids on ligand substitution reactions

  摘要：

  Ionic liquid solvents N-hexylpyridinium bistrifylimide ([C(6)pyr][Tf2N]] and 1-butyl-3-methylimidazolium hexafluorophosphate ([C(4)mim][PF6]) promoted the displacement of anionic ligands by pyridine derivatives in trans-(Ph3P)(2)Rh(CO)NO3 to a much greater extent than did dichloromethane. Thus, addition of a slight excess of 2-fluoropyridine to trans-(Ph3P)(2)Rh(CO)NO3 in [C(4)mim][PF6] gave a 29:71 product mixture of trans-(Ph3P)(2)Rh(CO)NO3:[trans-(Ph3P)(2)Rh(CO)(2-fluoropyridine)][NO3], while the ratio was 91:9 in dichloromethane. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.018