[PtCl2(N-(3-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine)] | 867313-12-0

• 英文名称: [PtCl2(N-(3-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine)]
• CAS: 867313-12-0
• 化学式: C₁₂H₁₇Cl₃N₂Pt
• 分子量: 490.719
• InChiKey: YGPWVUXPVBPCNS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 [PtCl2(N-(3-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine)] 在 sodium acetate 作用下， 以 甲醇 为溶剂， 以52%的产率得到[PtCl(N-(3-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine(-1H))]
  参考文献：
  名称：

  Synthesis and reactivity of cyclometallated platinum (II) compounds containing [C,N,N′] terdentate ligands: Crystal structures of [PtCl{(CH3)2N(CH2)3NCH(4-ClC 6H3)}], [PtCl{(CH3)2N(CH2)3NCH(2-ClC6H3)}] and [PtCl{(CH3)2N(CH2)3NCH(3-(CH3)C6H3)}]

  摘要：

  The reaction of compound CiS-[PtCl2(dmos)(2)] With ligands RCHN(CH2)(3)NMe2 (1a-1h) in which R is a phenyl group containing substituents such as Cl, F, Me, NO2 and MeO produced compounds [PtCl2{(CH3)(2)N(CH2)(3)NCHR}] (2), as mixtures of Z and E isomers. When treated with an equimolar amount of sodium acetate in refluxing methanol compounds 2 gave cyclometallated platinum compounds 3 containing a terdentate [C,N,N'] ligand. The obtained compounds were fully characterized including structure determinations for compounds 3a, 3b and 3e. The effects of the substituents in the regioselectivity of the cyclometallation reaction and the reactivity of 3a and 3b with mono and bidentate phosphines were also studied. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.038
• 作为产物：
  描述：

  dichlorobis(dimethyl sulfoxide)platinum(II) 、 N-(3-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine 以 甲醇 为溶剂， 以34%的产率得到[PtCl2(N-(3-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine)]
  参考文献：
  名称：

  Synthesis and reactivity of cyclometallated platinum (II) compounds containing [C,N,N′] terdentate ligands: Crystal structures of [PtCl{(CH3)2N(CH2)3NCH(4-ClC 6H3)}], [PtCl{(CH3)2N(CH2)3NCH(2-ClC6H3)}] and [PtCl{(CH3)2N(CH2)3NCH(3-(CH3)C6H3)}]

  摘要：

  The reaction of compound CiS-[PtCl2(dmos)(2)] With ligands RCHN(CH2)(3)NMe2 (1a-1h) in which R is a phenyl group containing substituents such as Cl, F, Me, NO2 and MeO produced compounds [PtCl2{(CH3)(2)N(CH2)(3)NCHR}] (2), as mixtures of Z and E isomers. When treated with an equimolar amount of sodium acetate in refluxing methanol compounds 2 gave cyclometallated platinum compounds 3 containing a terdentate [C,N,N'] ligand. The obtained compounds were fully characterized including structure determinations for compounds 3a, 3b and 3e. The effects of the substituents in the regioselectivity of the cyclometallation reaction and the reactivity of 3a and 3b with mono and bidentate phosphines were also studied. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.038