Hg2(N,N'-bis(3-imidazol-1-ylpropyl)naphthanelediimide)2I4*ferrocene | 1370421-29-6

• 英文名称: Hg2(N,N'-bis(3-imidazol-1-ylpropyl)naphthanelediimide)2I4*ferrocene
• CAS: 1370421-29-6
• 化学式: C₁₀H₁₀Fe*C₅₂H₄₄Hg₂I₄N₁₂O₈
• 分子量: 2059.83
• InChiKey: JUTBXKBWGXPGJS-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  N,N'-bis(3-imidazol-1-ylpropyl)naphthalenediimide 、 二茂铁 、 mercury(II) iodide 以 甲醇 、 氯仿 为溶剂， 以30%的产率得到Hg2(N,N'-bis(3-imidazol-1-ylpropyl)naphthanelediimide)2I4*ferrocene
  参考文献：
  名称：

  Structural Conformation and Optical and Electrochemical Properties of Imidazolyl‐Substituted Naphthalenediimide and Its Hg ^II , Cd ^II , and Cu ^II Halide Complexes

  摘要：

  AbstractA new end–core–end naphthalenediimide‐based ligand N,N′‐bis(3‐imidazol‐1‐yl‐propyl)naphthalene diimide (3‐imntd) was synthesized. Single crystals of the free ligand and its HgII, CdII, and CuII halide complexes were obtained. All the compounds were fully characterized by elemental analysis, IR spectroscopy, single‐crystal XRD, and DFT studies. The XRD and DFT calculations revealed three different kinds of conformations for 3‐imntd (cis, trans, and L). The variation in the ligand conformation and the resulting final structures of the coordination assemblies, M2L2 metallacycle, 1D zigzag chain, or ML metallacycle, seem to be induced by the different geometric characters of the coordination tetrahedra around the metal centers. The optical and electrochemical properties of the compounds were also investigated.

  DOI：

  10.1002/ejic.201101181