mer-[Fe(III)Br3(pyrazole)3] | 1400114-91-1

• 英文名称: mer-[Fe(III)Br3(pyrazole)3]
• CAS: 1400114-91-1
• 化学式: C₉H₁₂Br₃FeN₆
• 分子量: 499.793
• InChiKey: ZQZPQUMNODTTDV-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  吡唑 、 ferric(III) bromide 以 二氯甲烷 为溶剂， 反应 20.0h， 以10%的产率得到mer-[Fe(III)Br3(pyrazole)3]
  参考文献：
  名称：

  Structural and 57Fe-Mössbauer characterization of mononuclear ferrous and ferric pyrazole complexes

  摘要：

  The reactions of FeX3 (X = Cl and Br) and pz*H (pz*H = pyrazole, or substituted pyrazole) in CH2Cl2 have led to three types of mononuclear complexes: mer-[FeX3(pz*H)(3)], trans-[FeX2(pz*H)(4)](-) and trans-[FeX2(pz*H)(4)]. The latter type, containing Fe-II-centers results from spontaneous reduction of the Fe-III starting material. The X-ray crystal structures of eleven such complexes and the Fe-57-Mossbauer spectra of three of them are reported. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.052