[Ir(1,5-cyclooctadiene)(1,4-bis(methylthio)butane)]BF4 | 400777-23-3

• 英文名称: [Ir(1,5-cyclooctadiene)(1,4-bis(methylthio)butane)]BF4
• CAS: 400777-23-3
• 化学式: BF₄*C₁₄H₂₆IrS₂
• 分子量: 537.517
• InChiKey: WPKNBMUHTAOBFN-PHFPKPIQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1Z,5Z)-cycloocta-1,5-diene,iridium,tetrafluoroborate 、 2,7-二硫代辛烷 以 二氯甲烷 为溶剂， 以89%的产率得到[Ir(1,5-cyclooctadiene)(1,4-bis(methylthio)butane)]BF4
  参考文献：
  名称：

  Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins

  摘要：

  Mononuclear complexes [M(cod)(RS(CH2)(n)SR)]BF4 (M = Rh, Ir; n = 2-4)) were synthesized and characterized. The crystal structure of [Rh(cod){(CH3)(2)CHS(CH2)(4)SCH(CH3)(2)}]BF4 was determined by X-ray diffraction. The iridium complexes are catalytically active precursors in the hydrogenation of olefins. The effect of the length of the backbone between the two sulfur atoms and the group R bonded to sulfur was studied in the hydrogenation of itaconic acid and 1-hexene. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00623-5