[Cd(η2-4-ferrocenylbutyrate)2(1,1-(1,4-butanediyl)bis-1H-benzimidazole)]*(methanol) | 1240325-16-9

• 英文名称: [Cd(η2-4-ferrocenylbutyrate)2(1,1-(1,4-butanediyl)bis-1H-benzimidazole)]*(methanol)
• CAS: 1240325-16-9
• 化学式: CH₄O*C₄₆H₄₈CdFe₂N₄O₄
• 分子量: 977.058
• InChiKey: FEYLHFVHBRPYAP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 sodium 4-ferrocenylbutanoate 、 cadmium(II) acetate dihydrate 、 1,4-bis-(N-benzimidazolyl)butane 以 甲醇 、 水 为溶剂， 以53%的产率得到[Cd(η2-4-ferrocenylbutyrate)2(1,1-(1,4-butanediyl)bis-1H-benzimidazole)]*(methanol)
  参考文献：
  名称：

  New Cd(II), Zn(II) helical coordination polymers constructed from hybrid ligands 4-ferrocenylbutyrate and 1,1-(1,4-butanediyl)bis-1H-benzimidazole

  摘要：

  Self-assemblies of Cd(II) or Zn(II) salts with hybrid ligands sodium 4-ferrocenylbutyrate and 1,1-(1,4-butanediyl)bis-1H-benzimidazole (bbbm) gave rise to two new coordination polymers ([Cd(eta(2)-OOC(CH2)(3)Fc)(2)(bbbm)]center dot CH3OH}(n) (1) and {[Zn(OOC(CH2)(3)Fc)(eta(2)-OOC(CH2)(3)Fc)(bbbm)]center dot CH3OH}(n) (2) (Fe = (eta(5)-C5H5) Fe(eta(5)-C5H4)). Both polymers possess 1D helical chain structures with 21 screw axes along the b-direction although the coordination modes of the 4-ferrocenylbutyrate ligands and the coordination environments of the central metals in the two polymers are different. In addition, the redox properties of polymers 1 and 2 are also investigated and the results show that the formal potentials and the self-diffusion coefficients of the two polymers are close to each other. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2010.04.013