| 934185-50-9

• CAS: 934185-50-9
• 化学式: C₃₀H₂₆Cu₂N₆O₆
• 分子量: 693.665
• InChiKey: FPPVFSNVJVOGFW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  New magnetoactive copper complexes with Schiff’s bases

  摘要：

  Tridentate azomethine ligands with N2O and N-3 donor atoms and their copper complexes have been synthesized and characterized. Magnetochemical measurements in the temperature range of 5-300 K show that the change in the coordination environment induces the change in the sign of exchange coupling in the molecules of complexes.

  DOI：

  10.1134/s0036023606070096

文献信息

• Synthesis and magnetic properties of new binuclear Cu(II) complexes with tridentate azomethine ligands
  作者：A. S. Burlov、V. N. Ikorskii、A. I. Uraev、Yu. V. Koshchienko、I. S. Vasil’chenko、D. A. Garnovskii、G. S. Borodkin、S. A. Nikolaevskii、A. D. Garnovskii

  DOI：10.1134/s1070363206080214

  日期：2006.8

  New binuclear copper complexes of tridentate azomethine ligands with various combinations of N, O, and S donor centers were prepared by various procedures, including template synthesis. The magneto-chemical data obtained for the range 2-300 K suggest the occurrence of antiferromagnetic coupling in most of these chelates. The only exception is the complex containing N-tosyl and N-ethyl donor fragments, in which the ferromagnetic exchange is observed.