pentamethylcyclopentadienyliridium(III) PMe3(CH3)[CH3B(C6F5)3] | 351324-25-9

• 英文名称: pentamethylcyclopentadienyliridium(III) PMe3(CH3)[CH3B(C6F5)3]
• CAS: 351324-25-9
• 化学式: C₁₅H₂₉Cl₂IrP*C₁₉H₃BF₁₅
• 分子量: 1030.51
• InChiKey: FBRMJWARKKWDHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 pentamethylcyclopentadienyliridium(III) PMe3(CH3)[CH3B(C6F5)3] 以 not given 为溶剂， 生成 pentamethylcyclopentadienyliridium(III) PMe3 hydrido (tetrahydrofuran)[CH3B(C6F5)3]
  参考文献：
  名称：

  Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solution

  摘要：

  This report details our work in the area of C-H activation by cationic Ir(III) complexes. We highlight the previously reported chemistry of transition metal complexes of the type Cp-*(PMe3)Ir(R)(X) (Cp-* is pentamethylcyclopentadienyl or eta(5) -C5Me5; R = alkyl, hydrido; X = OSO2CF3, B(3,5-(CF3)(2)C6H3)(4))), and disclose new results concerning the production of these complexes using Lewis acids (LAs). Additionally, new work aimed at examining the mechanism of C-H activation by these complexes is presented. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(02)00192-9

文献信息

• Exceptionally Low-Temperature Carbon−Hydrogen/Carbon−Deuterium Exchange Reactions of Organic and Organometallic Compounds Catalyzed by the Cp*(PMe₃)IrH(ClCH₂Cl)⁺ Cation
  作者：Jeffery T. Golden、Richard A. Andersen、Robert G. Bergman

  DOI：10.1021/ja0155480

  日期：2001.6.1

  more useful, functionalized organic compounds, much effort has gone into developing mild methods for carrying out this transformation in solution. 1 Most of the classical methods for activating C-H bonds involve oxidative addition reactions with uncharged, electron-rich, coordinatively unsaturated metal centers (eq 1). Recently, however, several new C -H activation reactions have been discovered that

  由于金属介导的碳-氢键活化在将饱和烃转化为更有用的官能化有机化合物方面可以发挥作用，因此在开发用于在溶液中进行这种转化的温和方法方面付出了很多努力。1 大多数激活 CH 键的经典方法都涉及与不带电、富电子、配位不饱和金属中心的氧化加成反应（方程式 1）。然而，最近发现了几种新的 C-H 活化反应，它们发生在阳离子“亲电”晚期过渡金属中心，引起了对此类 CH 活化反应的兴趣（方程式 2）。2-8 大部分