Dichlorotetrakis(tetrahydrofuran)vanadium(III) pentachloro(tetrahydrofuran)stannate(IV) | 137253-75-9

• 英文名称: Dichlorotetrakis(tetrahydrofuran)vanadium(III) pentachloro(tetrahydrofuran)stannate(IV)
• CAS: 137253-75-9
• 化学式: C₄H₈Cl₅OSn*C₁₆H₃₂Cl₂O₄V
• 分子量: 778.357
• InChiKey: ZGWWXCHFPAPBBE-UHFFFAOYSA-G

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [VCl3(thf)3] 、 tetrachlorobis(tetrahydrofuran)tin(IV) 以 四氢呋喃 为溶剂， 生成 Dichlorotetrakis(tetrahydrofuran)vanadium(III) pentachloro(tetrahydrofuran)stannate(IV)
  参考文献：
  名称：

  Interaction of tin chlorides with iron, chromium and vanadium chlorides in tetrahydrofuran. Crystal structures of [Fe₂(µ-Cl)₃(thf)₆][SnCl₅(thf)], [Sn₂(µ-OH)₂Cl₆(thf)₂]·2thf and trans-[CrCl₂(thf)₄][SnCl₅(thf)]

  摘要：

  The reaction of FeCl3 with SnCl2 in tetrahydrofuran (thf) yields the salt [Fe2(mu-Cl)3(thf)6][SnCl5(thf)] 1. In the [Fe2(mu-Cl)3(thf)6]+ cation, two six-co-ordinate Fe2+ ions separated by an Fe ... Fe distance of 3.086(2) angstrom are bonded through three bridging Cl atoms. Compound 1 undergoes partial decomposition under reflux in thf to give [Fe4(mu-3-Cl)2(mu-Cl)4Cl2(thf)6] 2 and [SnCl4(thf)2]. The compound [Sn2(mu-OH)2Cl6(thf)2].2thf 3 is formed under the influence of moisture during the crystallization of [SnCl4(thf)2]. It is a dimeric complex of Sn(IV) in which each tin atom is surrounded octahedrally by three chlorine atoms, one thf molecule and two bridging hydroxide groups. An additional two thf molecules are hydrogen-bonded to the oxygen atoms of the hydroxide groups. By contrast with FeCl3, the reactions of [SnCl4(thf)2] with [MCl3(thf)3] (M = V or Cr) in thf give tin(IV) salts of the type trans-[MCl2(thf)4][SnCl5(thf)].

  DOI：

  10.1039/dt9910002429