| 438588-79-5

• CAS: 438588-79-5
• 化学式: C₂₂H₃₃OsP
• 分子量: 518.678
• InChiKey: CWCLUAOVKBKTNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 、 三甲氧基磷 以 甲苯 为溶剂， 以75%的产率得到cyclopenta-1,3-diene;ethenylbenzene;osmium(2+);trimethyl phosphite;tri(propan-2-yl)phosphane
  参考文献：
  名称：

  Hydride−Carbyne to Carbene Transformation in a Cyclopentadienyl−Osmium Complex:  An Alternative to the Single Hydride−C_α Migration

  摘要：

  Complexes OsH(eta(5)-C5H5)(Cequivalent toCPh)(EPh3)-((PPr3)-Pr-i) [E = Si (1), Ge (2)] react with 2.0 equiv of HBF4.OEt2 to give [OsH(eta(5)-C5H5)(equivalent toC-CH2Ph)((PPr3)-Pr-i)]-BF4 (3). Treatment of 3 with KOH affords OsH(eta(5)-C5H5)(=C=CHPh)((PPr3)-Pr-i) (5) in equilibrium with the metalated species OsH(eta(5)-C5H5)(o-C6H4CH=CH)((PPr3)-Pr-i) (7) (DeltaHdegrees = -3.6 +/- 0.2 kcal mol(-1) and DeltaSdegrees = -10.8 +/- 1.9 cal K-1 mol(-1) for the formation of 7). The addition of P(OMe)3 to the solution of the isomeric mixture leads to Os(eta(5)-C5H5{(E)-CH=CHPh}{P(OMe)(3)}((PPr3)-Pr-i) (8), which reacts with HBF4.OEt2 to give [Os(eta(5)-C5H5(=CHCH2Ph){P(OMe)(3)}((PPr3)-Pr-i)]BF4 (4).

  DOI：

  10.1021/om011077e
• 作为产物：
  描述：

  [OsH(η5-C5H5)(CCH2Ph)(CH(CH3)2)](BF4) 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 生成 、
  参考文献：
  名称：

  Hydride−Carbyne to Carbene Transformation in a Cyclopentadienyl−Osmium Complex:  An Alternative to the Single Hydride−C_α Migration

  摘要：

  Complexes OsH(eta(5)-C5H5)(Cequivalent toCPh)(EPh3)-((PPr3)-Pr-i) [E = Si (1), Ge (2)] react with 2.0 equiv of HBF4.OEt2 to give [OsH(eta(5)-C5H5)(equivalent toC-CH2Ph)((PPr3)-Pr-i)]-BF4 (3). Treatment of 3 with KOH affords OsH(eta(5)-C5H5)(=C=CHPh)((PPr3)-Pr-i) (5) in equilibrium with the metalated species OsH(eta(5)-C5H5)(o-C6H4CH=CH)((PPr3)-Pr-i) (7) (DeltaHdegrees = -3.6 +/- 0.2 kcal mol(-1) and DeltaSdegrees = -10.8 +/- 1.9 cal K-1 mol(-1) for the formation of 7). The addition of P(OMe)3 to the solution of the isomeric mixture leads to Os(eta(5)-C5H5{(E)-CH=CHPh}{P(OMe)(3)}((PPr3)-Pr-i) (8), which reacts with HBF4.OEt2 to give [Os(eta(5)-C5H5(=CHCH2Ph){P(OMe)(3)}((PPr3)-Pr-i)]BF4 (4).

  DOI：

  10.1021/om011077e