Cd(II)-(N^N-tripy)₂ | 1446441-04-8

• 英文名称: Cd(II)-(N^N-tripy)₂
• 英文别名: Cd(II)-(N^N-1,2,3-triazole-4-(2-pyridine))₂
• CAS: 1446441-04-8
• 化学式: C₃₄H₂₈CdCl₂Fe₂N₈O₈
• 分子量: 971.655
• InChiKey: XVTGNBNMPWIPAS-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  Cd(II)-(N^N-tripy)₂ 、 四丁基硫酸氢铵 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Multichannel recognition of hydrogen sulphate anion by a Zn(II)–triazole–pyridine complex bearing a ferrocenyl pendant

  摘要：

  Receptors ferrocene-triazole-pyridine triads assembled with Zn(II) or Cd(II) metal cations behave as chemosensor molecules for HSO4- anions through electrochemical and optical channels: the redox peak of the ferrocene/ferrocenium redox couple is shifted cathodically by 72-53 mV, and a new absorption band appeared in the UV-vis spectrum upon complexation with the HSO4- anion. Association constants, detection limits and stoichiometries of the recognition processes have been determined, whereas H-1 NMR experiments and density functional theory calculations are used to suggest the plausible binding mode taking place in the new supramolecular assembly formed.

  DOI：

  10.1080/10610278.2012.721883