[Rh(η4-cod){3-((R)-(phenyl)-ethylimino)-3H-indol-2-olato}] | 1417912-72-1

• 英文名称: [Rh(η4-cod){3-((R)-(phenyl)-ethylimino)-3H-indol-2-olato}]
• CAS: 1417912-72-1
• 化学式: C₂₄H₂₅N₂ORh
• 分子量: 460.381
• InChiKey: DGLVZXIUKCEOKA-JCUGFHOXSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di-μ-acetato-bis(η4-1,5-cyclooctadiene)dirhodium(I) 、 3-{(R)-(phenyl)ethylimino}-1,3-dihydro-indol-2-one 以 甲醇 、 苯 为溶剂， 反应 0.17h， 以71%的产率得到[Rh(η4-cod){3-((R)-(phenyl)-ethylimino)-3H-indol-2-olato}]
  参考文献：
  名称：

  Syntheses, spectroscopy, and X-ray structures of 3-{(R)-(Ar)-ethylimino}-1,3-dihydro-indol-2-one (Ar = Ph, MeOC₆H₄, BrC₆H₄, 1-naphthyl) and [Rh(η⁴-cod){3-((R)-(Ar)-ethylimino)-3H-indol-2-olato}]

  摘要：

  Condensation of 1H-indole-2,3-dione (isatin) with (R)-(Ar)-ethylamines gives enantiopure Schiff bases, 3-{(R)-(Ar)-ethylimino}-1,3-dihydro-indol-2-one (HL) {Ar?=?Ph (HL1), 2-MeOC6H4 (HL2), 4-MeOC6H4 (HL3), 4-BrC6H4 (HL4), and 1-naphthyl (HL5)}. The Schiff bases readily coordinate to [Rh(mu-O2CMe)(?4-cod)]2 (cod?=?1,5-cyclooctadiene) to give mononuclear [Rh(?4-cod){3-((R)-(Ar)-ethylimino)-3H-indol-2-olato}] {Ar?=?Ph (1), 4-MeOC6H4 (2), and 4-BrC6H4 (3)}, respectively. The Schiff bases and complexes have been fully characterized by IR, UV-Vis, 1H-NMR, mass, and circular dichroism (CD) spectrometry. Polarimetry and CD measurements show the enantiopurity of the Schiff bases as well as the complexes. 1H NMR measurements reveal slow conversion of the lactam to the enol form of the Schiff bases in solution. In the solid state the lactam form dominates as shown by crystal structures of HL1 and HL4. While gross structural features of both are similar, the molecules differ significantly in the relative orientations of the aryl and lactam rings. The difference is mostly rotation about the N2C9 bond with different C8N2C9C11 torsion angle of +89.77(12)degrees for HL1 and C2N2C9C11 of +106.8(3)degrees for HL4.

  DOI：

  10.1080/00958972.2012.738293