trans-(η(5):η(5)-fulvalene)Mo2(CO)4(P(cyclohexyl)3)2 | 168414-77-5

• 英文名称: trans-(η(5):η(5)-fulvalene)Mo2(CO)4(P(cyclohexyl)3)2
• CAS: 168414-77-5
• 化学式: C₅₀H₇₄Mo₂O₄P₂
• 分子量: 992.963
• InChiKey: MJXSWGKAGNOVKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis,cis-(η(5):η(5)-fulvalene)Mo2(CO)4(Cl)2(P(cyclohexyl)3)2 在 sodium 作用下， 以 四氢呋喃 为溶剂， 以56%的产率得到trans-(η(5):η(5)-fulvalene)Mo2(CO)4(P(cyclohexyl)3)2
  参考文献：
  名称：

  含立体键位的膦的钼钼钼键合（富勒烯）二钼羰基配合物的合成与表征

  摘要：

  The new metal-metal-bonded (fulvalene)dimolybdenum carbonyl complexes FVMo2(CO)(4)L(2) (L = PPh(3), PCy(3), PXy(3); Xy = 3,5-dimethylphenyl) were synthesized via (af hydride hydrogen atom abstraction from FVMo2(CO)(4)L(2)H(2) (L = PPh(3), PXy(3)) by trityl radicals, (b) sodium reduction of FVMo2(CO)(4)L(2)Cl(2) (L = PPh(3), PCy(3), PXy(3)), and (c) oxidation of the dianions [FVMo2(CO)(4)L(2)](2-) (L = PPh(3), PCy(3)). The compounds were characterized by IR, UV-vis, and H-1, C-13{H-1} and P-31{H-1} NMR spectroscopy, and the spectroscopic data are in all cases consistent with structures containing the phosphines in positions trans to the Mo-Mo bond. The UV-vis spectra of trans-FvMo(2)(CO)(4)L(2) (L = PPh(3), PCy(3), PXy(3)) all exhibit a sigma --> sigma* transition at 374 nm, suggesting that the phosphines influence neither sterically nor electronically the Mo-Mo bond strength. Evidence for radical intermediates was found when FvMo(2)(CO)(4)(PPh(3))(2) was prepared from FvMo(2)(CO)(4)(PPh(3))(2)H-2.

  DOI：

  10.1021/om00009a011