| 31320-66-8

• CAS: 31320-66-8
• 化学式: C₁₈H₁₈N₂O₆V₂
• 分子量: 460.234
• InChiKey: WBRDLHNMOIRFTO-RKAHVXQLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(acetylacetonate)oxovanadium 、 水杨醛 、 C.I.酸性橙108 以 二氯甲烷 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Characterization of oxovanadium (IV)–Schiff-base complexes and those bound on resin, and their use in sulfide oxidation

  摘要：

  Oxovanadium (IV)-Schiff-base complexes and those bound on Merrifield resin as a polymer support were prepared for their characterization and their use as catalyst in oxidation of methyl phenyl sulfide. Schiff bases were prepared with use of salicylaldehyde and 2,4-dihydroxybenzaldehyde as the aldehydes and 2-aminoethanol, L-phenylalaninol, L-histidinol, and L-phenylalanine as the counterparts. Oxovanadium (IV) complexes made up of these Schiff bases and those bound on the resin were spectroscopically characterized. The polymer-supported Schiff-base complexes in the presence of tertiary-butylhydroperoxide converted the sulfide to the corresponding sulfoxide in 80-90% yield in CDCl3 in 90 min. They afforded slightly lower rates of oxidation than the corresponding monomeric complexes. They converted the sulfide in a stereoselective manner yielding the sulfoxide in enantiomeric excess (the highest value of 40%). The polymer-supported complexes and the corresponding monomers achieved almost the same enatiometric excesses with each other. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.12.031