3-(tert-butyl)-1,1,5,5-tetraethyl-1H,5H-1l4,2l3,5l4,6l4-pyrazolo[2,1-c][1,6,3,4,2,5]dioxadiazadiborepine | 217324-51-1

• 英文名称: 3-(tert-butyl)-1,1,5,5-tetraethyl-1H,5H-1l4,2l3,5l4,6l4-pyrazolo[2,1-c][1,6,3,4,2,5]dioxadiazadiborepine
• CAS: 217324-51-1
• 化学式: C₁₆H₃₂B₂N₂O₂
• 分子量: 306.064
• InChiKey: VAHFYILOVJBTOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  3-(tert-butyl)-1,1,5,5-tetraethyl-1H,5H-1l4,2l3,5l4,6l4-pyrazolo[2,1-c][1,6,3,4,2,5]dioxadiazadiborepine 以 neat (no solvent) 为溶剂， 生成 4,4,8,8-tetraethylpyrazabole
  参考文献：
  名称：

  Catalyzed reaction of triethylborane with pyrazole

  摘要：

  The reaction of triethylborane with pyrazole leading to 4,4,8,8-tetraethylpyrazabole was found to be catalyzed by carboxylic acids. 2,2'-Dimethylpropanoic (pivalic) or benzoic acids act as catalysts in this reaction. Intermediates occurring in the catalytic cycle have been isolated and characterized by NMR as well as IR spectroscopy, and in one case also by X-ray crystallography. The mechanism of the reaction is proposed. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00705-6
• 作为产物：
  描述：

  triethylborane pyrazole complex 以 正庚烷 为溶剂， 生成 3-(tert-butyl)-1,1,5,5-tetraethyl-1H,5H-1l4,2l3,5l4,6l4-pyrazolo[2,1-c][1,6,3,4,2,5]dioxadiazadiborepine
  参考文献：
  名称：

  Catalyzed reaction of triethylborane with pyrazole

  摘要：

  The reaction of triethylborane with pyrazole leading to 4,4,8,8-tetraethylpyrazabole was found to be catalyzed by carboxylic acids. 2,2'-Dimethylpropanoic (pivalic) or benzoic acids act as catalysts in this reaction. Intermediates occurring in the catalytic cycle have been isolated and characterized by NMR as well as IR spectroscopy, and in one case also by X-ray crystallography. The mechanism of the reaction is proposed. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00705-6