(N,N'-ethylene bis(2-oxy-acetophenonimine))Cu2Cl2 | 19362-09-5

• 英文名称: (N,N'-ethylene bis(2-oxy-acetophenonimine))Cu2Cl2
• CAS: 19362-09-5
• 化学式: C₁₈H₁₈Cl₂Cu₂N₂O₂
• 分子量: 492.351
• InChiKey: RIJJWUKSJGSLRK-DRLFUFNGSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (N,N'-ethylene bis(2-oxy-acetophenonimine))Cu2Cl2 在 水 作用下， 生成 copper(II) chloride hexahydrate 、 (copper(II))(di-methyl-Salen)
  参考文献：
  名称：

  Bhattacharya, P. K., Journal of the Indian Chemical Society, 1982, vol. 59, p. 505 - 509

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 N,N'-二(2-羟基-alpha-甲基苄亚基)乙二胺 在 三乙胺 作用下， 以 甲醇 为溶剂， 以0.506 g的产率得到(N,N'-ethylene bis(2-oxy-acetophenonimine))Cu2Cl2
  参考文献：
  名称：

  Synthesis and electrocatalytic properties of a dinuclear copper(II) complex for generating hydrogen from acetic acid or water

  摘要：

  The reaction of CuCl(2)2H(2)O and a tetradentate amine phenol ligand affords a dinuclear Cu(II) complex, 1, a new molecular electrocatalyst, whose structure has been determined by X-ray crystallography. Electrochemical studies show that 1 can efficiently produce hydrogen from acetic acid with a turnover frequency (TOF) of 50.1 (in DMF) or from water with a TOF of 104.3 (pH7.0) moles of hydrogen per mole of catalyst per hour.

  DOI：

  10.1080/00958972.2014.998657
• 作为试剂：
  描述：

  水 在 (N,N'-ethylene bis(2-oxy-acetophenonimine))Cu2Cl2 作用下， 以 aq. phosphate buffer 、 乙腈 为溶剂， 反应 1.0h， 生成 氢气
  参考文献：
  名称：

  Synthesis and electrocatalytic properties of a dinuclear copper(II) complex for generating hydrogen from acetic acid or water

  摘要：

  The reaction of CuCl(2)2H(2)O and a tetradentate amine phenol ligand affords a dinuclear Cu(II) complex, 1, a new molecular electrocatalyst, whose structure has been determined by X-ray crystallography. Electrochemical studies show that 1 can efficiently produce hydrogen from acetic acid with a turnover frequency (TOF) of 50.1 (in DMF) or from water with a TOF of 104.3 (pH7.0) moles of hydrogen per mole of catalyst per hour.

  DOI：

  10.1080/00958972.2014.998657