Cu(N-quinolin-8-yl-naphthtalene-2-sulfonamide(1-))(2,2'-bipyridine)Cl | 641617-62-1

• 英文名称: Cu(N-quinolin-8-yl-naphthtalene-2-sulfonamide(1-))(2,2'-bipyridine)Cl
• CAS: 641617-62-1
• 化学式: C₂₉H₂₁ClCuN₄O₂S
• 分子量: 588.576
• InChiKey: IDDPFLBLRDZFCD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 N-(quinolin-8-yl)naphthalene-2-sulfonamide 、 copper dichloride 在 NH₃ 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 Cu(N-quinolin-8-yl-naphthtalene-2-sulfonamide(1-))(2,2'-bipyridine)Cl
  参考文献：
  名称：

  Structural characterisation and nuclease activity of mixed copper(II) complexes with sulfonamides and bipyridil

  摘要：

  Mixed copper complexes have been synthetised through reaction of Cu(II) salts with bipyridil and N-quinolin-8-yl-p-toluenesulfonamide (Hqtsa), N-quinolin-8-yl-benzenesulfonamide (Hqbsa) or N-quinolin-8-yl-naftalenesulfonamide (Hqnsa). Single crystal X-ray diffraction structure determination shows that copper cations are five-coordinated, one complex have distorted bipyramidal trigonal geometry and the other have a distorted square-pyramid. The FT IR and EPR spectra are also reported. Electrophoresis results show that the synthetised complexes in the presence of ascorbate and hydrogen peroxide are chemical nucleases. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00236-6