[(eta.5-pentamethylcyclopentadienyl)Rh(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane) | 1192801-54-9

• 英文名称: [(eta.5-pentamethylcyclopentadienyl)Rh(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane)
• CAS: 1192801-54-9
• 化学式: C₃₆H₄₈Cl₄P₂Rh₂
• 分子量: 890.348
• InChiKey: STTDBMWAICQRSS-CCAURHDSSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(eta.5-pentamethylcyclopentadienyl)Rh(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane) 以 乙腈 为溶剂， 生成 [C5Me5Rh(Cl)(P,P'-diphenyl-1,4-diphospha-cyclohexane)][PF6]
  参考文献：
  名称：

  Group 9 half-sandwich complexes containing the unique P,P′-diphenyl-1,4-diphospha-cyclohexane ligand: Synthesis, X-ray structure analyses and spectroscopic studies

  摘要：

  We wish to report the synthesis and characterization of Group 9 metal complexes with the novel P,P'-diphenyl-1,4-diphospha-cyclohexane (dpdpc) ligand. The complexes are readily prepared by direct ligand substitution reactions from the dichloro-bridged binuclear complexes, [{eta(5)-Cp*M(Cl)(2)}(2)]. The complexes include: [eta(5)-Cp*Rh(Cl)(2)](2)(mu-dpdpc) (1), [eta(5)-Cp*Ir(Cl)(2)](2)(mu-dpdpc) (2), and [eta(5)-Cp*Rh(Cl)(dpdpc)]PF6 (3). The structures for all three complexes are supported by H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy as well as elemental analysis. The molecular structures of 1 and 3 have also been established by single-crystal X-ray analysis. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.023
• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 P,P'-diphenyl-1,4-diphospha-cyclohexane 以 乙醇 为溶剂， 以45%的产率得到[(eta.5-pentamethylcyclopentadienyl)Rh(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane)
  参考文献：
  名称：

  Group 9 half-sandwich complexes containing the unique P,P′-diphenyl-1,4-diphospha-cyclohexane ligand: Synthesis, X-ray structure analyses and spectroscopic studies

  摘要：

  We wish to report the synthesis and characterization of Group 9 metal complexes with the novel P,P'-diphenyl-1,4-diphospha-cyclohexane (dpdpc) ligand. The complexes are readily prepared by direct ligand substitution reactions from the dichloro-bridged binuclear complexes, [{eta(5)-Cp*M(Cl)(2)}(2)]. The complexes include: [eta(5)-Cp*Rh(Cl)(2)](2)(mu-dpdpc) (1), [eta(5)-Cp*Ir(Cl)(2)](2)(mu-dpdpc) (2), and [eta(5)-Cp*Rh(Cl)(dpdpc)]PF6 (3). The structures for all three complexes are supported by H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy as well as elemental analysis. The molecular structures of 1 and 3 have also been established by single-crystal X-ray analysis. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.023