| 1385826-12-9

• CAS: 1385826-12-9
• 化学式: C₄₂H₃₈Fe₂N₂O₆S₂
• 分子量: 842.6
• InChiKey: FYUYQFDUGJTNEN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  十二羰基三铁 、 8-N,9-N-bis[2,6-di(propan-2-yl)phenyl]-2,3-dithiatetracyclo[5.5.2.04,13.010,14]tetradeca-1(13),4,6,10(14),11-pentaene-8,9-diimine 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Design, synthesis and characterization of a modular bridging ligand platform for bio-inspired hydrogen production

  摘要：

  Synthesis and characterization of a novel type of ambident bridging ligands joining together the functional prerequisites for visible-light absorption, photoinduced electron transfer and catalytic proton reduction is presented. This class of compounds consists of a chromophoric 1,2-diimine-based pi-acceptor site and a rigid polyaromatic dithiolate chelator. Due to the presence of a common conjugated linker moiety with an intrinsic two-electron redox reactivity and a suitable orbital coupling of the subunits, a favourable situation for vectorial multielectron transfer from attached electron donors to a catalytic acceptor site is provided. As an example for the application of this kind of bifunctional ligand systems, a [FeFe]-hydrogenase enzyme model compound is prepared and structurally characterized. Electrocatalytic hydrogen formation with this complex is demonstrated. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.04.034